Synthesis, Structure and Properties of a 2D Cadmium(II) Coordination Polymer Based on Fluconazole and Isophthalate Ligands

نویسندگان

  • Gang-Hong Pan
  • Jing-Niu Tang
  • Xian-Hong Yin
  • Zhong-Jing Huang
چکیده

A Cd(II) complex based on fluconazole and isophthalate ligands, {[Cd(HFlu)(IPA)(H2O)]·H2O}n (1), (HFlu = fluconazole; H2IPA = isophthalic acid) has been synthesized. Single-crystal X-ray analysis reveals that complex 1 has a 2D network structure including unusual triple hydrogen bonds between hydroxyl and triazolyl groups. The complex has also been characterized by IR, UV/Vis and fluorescence spectroscopy, elemental analysis, and thermogravimetry.

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تاریخ انتشار 2013